87 92 624 Special grease

/ 9-3 (9400) / 1998 / 0. General / Chemicals / Technical data / 87 92 624 Special grease

Specifications

Shell Stamina grease 0233. Low friction grease. 300 gramme cartridge.

Saab application

Inner drive joint, type tripod.

Packaging

Transport

No restrictions apply when transporting this product.

Directives

Prolonged or repeated skin contact may cause skin irritation. Avoid skin contact.

Material safety data sheet

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Trade name	Shell Stamina 0233
Application	Lubrication grease
Manufacturer - supplier	AB Svenska Shell Avd Hälsa & Miljö 167 80 BROMMA Tel: +46 (0) 8-555 480 00 Tel (emergency): Universitätsklinik Mainz hotline +49-6131/19240 or 112 (poison advice)

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient	CAS-no.	Weight %	Hazard class/comments
Highly refined mineral oil, PCA conc. < 3% by IP346	-	80-100	EK
Diurea thickener	-		EK
Long-chain barium sulfonate	-	<2	Xn, R20/22-R38-R41
Diphenylamine	122-39-4	<0.5	T, R23/24/25, R33
Function-improving additives	-

Comments on composition

The classification of barium sulfonate above is based on the classification of barium salts in the KIFS substance list and information provided by the supplier. Since the concentration of barium is less than 1%, this product should not be classed as harmful (note 1 in the KIFS substance list). The constituent highly refined mineral oil includes the following CAS no: 64742-65-0, 64742-62-7 and 64742-52-5. These oils contain <3% (w/w) DMSO extract, measured according to IP 346, and should therefore not be classified as carcinogenic (note L in KIFS substance list).

Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment

HAZARDS IDENTIFICATION

Contains diphenylamine, for which the exposure limit is specified. Contains mineral oil for which the exposure limit for oil mist is applied. Prolonged or repeated exposure may cause skin inflammation (dermatitis). Spent grease can contain harmful contaminants. Not classified as flammable, although combustible. The product is not readily biodegradable. Can bioaccumulate.

FIRST AID MEASURES

Inhalation	In case of dizziness or nausea, remove the casualty to fresh air. Seek medical advice.
Skin	Take off immediately contaminated clothing and wash the skin with soap and water. Seek medical advice if irritation persists. If high pressure injection of the product occurs, seek immediate medical advice/visit hospital.
Eyes	Flush eyes with plenty of water. Seek medical advice if irritation persist.
Ingestion	DO NOT induce vomiting. Do not give anything to eat or drink. Seek medical advice if recovery is not quick.
Medical information	Treat symptomatically. Aspiration into lungs may cause chemically-induced pneumonia. Dermatitis may result from prolonged or repeated exposure.

FIRE-FIGHTING MEASURES

Suitable extinguishing media	Foam or powder. Carbon dioxide, sand or earth can be used for small fires. Do not use water jet.
Fire and explosion risks	Combustion is likely to produce a complex mixture of fumes and air-borne particles, including carbon monoxide, sulphur dioxide and unidentified organic and inorganic compounds.
Other information	Suitable protective equipment and breathing apparatus with fresh air supply must be used if fighting a fire in a confined area.

SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions	Avoid contact with skin. Wear chemically-resistant gloves and boots.
Environmental precautions	Prevent release into drains, ditches and watercourses. Notify local authorities if release cannot be prevented.
Methods for cleaning up	For small spillages, collect in a suitable, clearly-marked container for disposal or recycling. For large spillages, prevent spreading by confining with sand, earth or other suitable material. Take up the product directly or using an absorbent material. Dispose of in the same way as for small spillages.

HANDLING AND STORAGE

Handling	If the product is handled in drums, wear protective shoes and use suitable handling equipment. Take precautions against spillage.
Storage	Store in a cool, dry, well-ventilated area. Use correct, labelled, sealable containers. Avoid direct sunlight, sources of heat and strong oxidizing agents. Storage temperature 0°C minimum, 50°C maximum. Store in containers made of sheet steel or high-density polyethene (HDPE). Do not use containers made of PVC or with a PVC lining.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical identity	Limit
-	-

Control procedures	The occupational exposure limit for oil spray, including oil fumes, is 1 mg/m³. Use local extraction equipment if there is a risk of inhaling vapours, mist or aerosols. Wash hands before eating or drinking.
Respiratory equipment	Not normally required. If oil mist is likely, use a full-face or half-face mask with combifilter (gas/vapours and particles).
Eye protection	Wear eye/face protection in case of risk of splashes or if the product is handled under pressure.
Hand protection	PVC or nitrile rubber gloves. When handling heated product, protect the hands and body against splashes.
Skin protection	Avoid all forms of skin contact. Wear an overall to prevent contaminating your own clothes. Wash overalls and underclothes regularly. Wear protective clothing or PVC apron in case of risk of splashes.

PHYSICAL AND CHEMICAL PROPERTIES

Form/state	Semi-solid at room temperature	Odour	Mild
Colour	Yellow	Density	950 kg/m³ at 15°C
Flash point	>200°C (COC)	Barium content (weight %)	< 0.1
Solubility in water	Negligible	Drop point	> 260°C

10.

STABILITY AND REACTIVITY

Stability	Stable. Avoid very high temperatures and direct sunlight.
Reacts with	Strong oxidizing agents.
Hazardous decomposition products	Hazardous decomposition products are not expected to form under normal storage.

11.

TOXICOLOGICAL INFORMATION

Acute oral toxicity	LD50, expected value	> 5000 mg/kg
Acute dermal toxicity	LD50, expected value	> 2000 mg/kg
Other toxicological information	Prolonged or repeated contact with this product may defat the skin, especially at elevated temperatures. This may cause irritation and possible skin inflammation (dermatitis), especially as a result of poor hygiene. Minimize skin contact. Spent grease can contain harmful contaminants that have formed during use. The concentrations of such contaminants depends on the use and these may pose a hazard to health and the environment. ALL used grease must be handled with great care and skin contact avoided as far as possible.

General	Toxicological data especially for this product has not been established. The information is based on knowledge of the components and the toxicology of similar products.
Inhalation	Inhalation of vapours, mist or aerosols may cause mild irritation of the respiratory tract.
Skin	Expected to be mildly irritating.
Eyes	Expected to be mildly irritating.
Ingestion	Low acute toxicity.
Sensitization	Not expected to be sensitizing to skin.
Cancer	This product is based on mineral oils that have shown to be non-carcinogenic in animal skin painting studies. The other components are not associated with carcinogenic effects.
Mutagen effects	Not mutagen.

12.

ECOLOGICAL INFORMATION

Mobility	The product floats on water. Semi-solid under normal conditions. In case of spillage into the environment, the product will be strongly absorbed by soil particles.
Degradability	The product is not readily biodegradable. The main components are expected to be potentially biodegradable, but the product contains components that may persist in the environment.
Accumulation	Risk of bioaccumulation cannot be ruled out.
Ecotoxicity	The product is not expected to be toxic to aquatic organisms (expected LC/EC50 > 100 mg/l). (LD/EC50 as the nominal amount of product required to prepare aqueous test extract.)
Other damaging effects	May contaminate aquatic organisms.
Information	Ecotoxicological data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of similar products.

13.

DISPOSAL CONSIDERATIONS

Disposal considerations

Waste and used product that cannot be recycled must be treated as hazardous waste. Must only be transported by licensed carries. Exception: license not required if the person carrying on the activities in which the hazardous waste is produce transports the hazardous waste themselves and the quantity of lubricant being transported during a year is less than 2 barrels (400 litres). Persons intending to transport their own waste should inform the county administrative board. Waste from the product must not be allowed to pollute the ground or water, or be released into the environment. The type of hazardous waste is specified by EWC codes. The codes for oil waste are based on application and constituent base oil. Data on applications and constituent base oils can be found under headings 1 and 2 of the material safety data sheet. A list of EWC codes for hazardous waste is available in the regulations on hazardous waste, SFS 1996:971 (in Swedish). Suitable classification of waste is the responsibility of the user. Examples of EWC codes for waste oil: 12 01 07 mineral-based machining oils free of halogens (except emulsions and solutions), 12 01 09 machining emulsions and solutions free of halogens, 12 01 10 synthetic machining oils, 13 01 06 hydraulic oils, containing mineral oils 13 01 07 other hydraulic oils, 13 02 03 other engine, gear & lubricating oils, 13 03 04 synthetic insulating and heat transmission oils and other liquids, 13 03 05 mineral insulating and heat transmission oils, and 13 06 01 oil waste not otherwise specified.

14.

TRANSPORT INFORMATION

Road (ADR)	UN-no. Hazardous goods Marg no.	Class: free	Label Hazard no.
Rail (RID)	UN-no.	Class: free	Label Hazard no.
Sea (IMDG)	UN-no. Class: free	Page Label	Packing group:
IATA (air)	UN-no.	Class: free	Label
Other transport information	Not classified as dangerous goods according to IMO or ADR/RID.

15.

REGULATORY INFORMATION

R-phrases	N/A.
S-phases	N/A.
Information	Not classified as harmful or dangerous for the environment according to Swedish chemical legislation.

16.

OTHER INFORMATION

Supplier notes	This document contains important information on the safe storage, handling and use of this product. The information must be submitted to the person responsible for safety issues at the workplace. The information in this document is based on current knowledge and is only intended for use for health, safety and environmental purposes. The information is not a specification of the product and must not be considered as a guarantee of any specific properties.
Issuer	Marita Nilsson
Replaces	1998-08-14
Issued	2000-05-12

87 92 624 Special grease

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