SAAB WIS ONLINE

30 30 699 Adhesive kit rear window CV

30 30 699 Adhesive kit rear window CV


Specifications

1 Betaseal 1400 (1K), 300 ml

1 Betaprime 5001, 30 ml

1 Betawipe VP 04604, 30 ml 1 Nozzle 1 Primer applicator 1 Cleaning cloth

Saab application

For glued rear window on Saab 900 Convertible M95-.

Packaging

1

Transport

No restrictions apply when transporting this product.

Directives

Contains isocyanates. Repeated or prolonged exposure with scratched or sensitive skin may cause allergies.

Material safety data sheet


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product name

Betaseal 1400

Manufacturer - supplier

Gurit Essex AG

Freienbach, Switzerland

Distributer

SAAB-ANA Konsult AB

Box 1030

611 29 NYKÖPING

Tel: +46 (0) 155-24 94 50



2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient

CAS-no.

Content (%)

Hazard symbol/R-phrases

Diphenylmethane-4,4-diisocyanate (MDI)

101-68-8

<1 (approx. 0.2)

Xn; R20/21 Xi; R36, R42/43

White spirit

8030-30-6

1

Fo: R10



Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment



3. HAZARDS IDENTIFICATION

Health hazards

Not subject to labelling in accordance with KIFS 1994:12. The level of MDI is such that a certain risk of sensitization cannot be completely ruled out. Persons already sensitized may react with the constituent MDI.

Fire hazards

Not flammable.



4. FIRST AID MEASURES

Inhalation

Fresh air and rest. In case of breathing difficulties, seek medical advice. In case of grave symptoms - artificial respiration if necessary and take immediately to hospital.

Skin

Take off immediately contaminated clothing. Wash carefully with soap and water. In case of symptoms, seek medical advice.

Eyes

Flush immediately with water. Seek medical advice if symptoms persist.

Ingestion

Seek medical advice if a large amount has been swallowed.

Information for physicians

Risk of asthmatic breathing difficulties on inhalation.



5. FIRE-FIGHTING MEASURES

General information

Produces vapours, which can form an explosive mixture with air, at temperatures below room temperature. The vapours are more dense than air and can collect in low-lying areas.

Suitable extinguishing media

Extinguish fires with foam, powder, water spray or carbon dioxide.

Safety precautions

Move or cool with water containers in the vicinity of fire.

Hazardous decomposition products

Combustion of the contents produces toxic fumes. Wear protective respiratory equipment.



6. SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions

Provide good ventilation. Avoid direct contact with the product. Be aware of the risk of ignition and explosion.

Environmental precautions

Prevent release into drains.

Methods for cleaning up

Soak up with a suitable non-flammable, absorbent material.



7. HANDLING AND STORAGE

Handling

Ensure good ventilation.

Storage

Keep containers tightly closed in a dry place between 15 and 30°C.



8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Advice for safe handling

Use only in well-ventilated places. Work procedures should be designed to avoid direct contact with the product. Provisions for eye flushing must be provided.

Technical safety precautions

In case of insufficient ventilation, provide mechanical ventilation or spot extraction.

Personal protection equipment

In case of insufficient ventilation, wear a full-face respirator with type A (brown) gas filter and type II b dust filter. In case of risk of direct contact, wear protective gloves, eye/face protection and protective clothing.



9. PHYSICAL AND CHEMICAL PROPERTIES

Form/state

Polyurethane-based paste

Odour

of solvent

Colour

Black

Solubility in water

Insignificant

Density

1.22 g/cm 3

Flash point

>150 °C



10. STABILITY AND REACTIVITY

Stability

Constituent isocyanates can react with water, amines, alcohols and acids. Heating can cause the release of harmful substances - even from hardened material.



11. TOXICOLOGICAL INFORMATION

Inhalation

The constituent isocyanate is not particularly volatile and the product only contains very small amounts. The risk of exposure is therefore very small but does exist in case of heating or handling very large quantities. Inhalation of the constituent isocyanate may cause stinging and a prickling sensation in the respiratory system, and even nausea and vomiting. May produce influenza-like symptoms, such as soar throat, coughing, fever, shivers, headache and muscular aches. May cause asthmatic breathing difficulties. Note that hypersensitive persons can experience breathing problems at very low concentrations, even under the set limits, and that symptoms may be delayed, appearing several hours after exposure.

Skin

Small risk allergic eczema, especially for persons already sensitized.

Eyes

Causes stinging on contact with the eyes.

Toxicological data

Diphenylmethane-4,4´-diisocyanate; LD50 oral, rat >4700 mg/kg; LC50 inhalation, rat 178 mg/m 3 ; allergen.



12. ECOLOGICAL INFORMATION

N/A

13. DISPOSAL CONSIDERATIONS

Disposal considerations

The handling of adhesive waste is governed by the provisions on environmentally dangerous waste (SFS 1985:841)



14. TRANSPORT INFORMATION

Transport name

Not classed for transport according to following regulations. (FN, IMDG, ADR/RID, DGR)



15. REGULATORY INFORMATION

Hazard symbols

Not classed. Must be labelled: Contains isocyanates. Refer to information from the manufacturer.



16. OTHER INFORMATION

Sources of information

The information on constituent isocyanate has primarily been taken from the following references:

1. Skyddsblad nr 84, safety sheet for chemical products, Association of Swedish Chemical Industries.

2. Sax's dangerous properties of industrial materials, R.J Lewis (Ed.), Van Nostrand Reinhold, New York, 1992.

General information

Note: When working with products containing isocyanates, observe the provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics (AFS 1993:4). The provisions cover the design of work premises, protective equipment, medical check-up of the persons working with thermosetting plastics, checking air pollutants and suchlike.

Issued

1995-06-26




Material safety data sheet


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product name

BETAPRIME 5001

Manufacturer - supplier

SAAB-ANA Konsult AB

Box 1030

611 29 NYKÖPING

Tel: +46 (0) 155-24 94 82

Fax: +46 (0) 155-24 94 71

Tel (emergency): 112



2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient

CAS-no.

Content (%)

FM

FB

FH

R-phrases

Carbon black

1333-86-4

1-15

Ethylacetate

41-78-6

1-10

Xi

R11-36-66-67

Toluene

108-88-3

1-12.5

Xn

R20

Methoxybutyl acetate

4435-53-4

1-20

Xi

R36

Methyl ethyl ketone

78-93-3

20-50

Xi

R36-66-67

Solvent naphtha (petroleum), light

64742-95-6

1-2

N

Xn

R10-65-37-66-517/5



Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment



3. HAZARDS IDENTIFICATION

Health hazards

Irritating to eyes. Defats the skin and after prolonged or repeated contact may cause skin to dry and crack. Inhalation of high concentrations may cause dizziness, headaches and nausea.

Fire hazards

Highly flammable.



4. FIRST AID MEASURES

Other information

Take off contaminated clothing immediately.

Inhalation

Move the casualty into fresh air. Seek medical advice immediately. Effects may be delayed. Keep the casualty warm and allow to rest. Perform artificial respiration if the casualty stops breathing or breathes irregularly.

Skin

Wash skin immediately with soap and water. Seek medical advice if irritation persists.

Eyes

Flush eyes immediately with plenty of water for several minutes. Hold eyes wide open. Seek medical advice immediately.

Ingestion

Do not induce vomiting. Seek medical advice immediately.



5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Foam or powder. Large fires can be extinguished with water spray.

Fire/explosions risks

Vapours can form an explosive mixture with air. In case of fire, harmful and irritating gases can form (e.g. carbon and nitrous oxides).

Special protective equipment for firefighters

Complete protective equipment including respiratory equipment

Other information

Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.



6. SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions

Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).

Environmental precautions

Keep the product away from drains, the ground and watercourses. Contact the appropriate authority immediately if the product enters drains, lakes or watercourses.

Methods for cleaning up

Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Place in suitable, open container. Keep contents moist. Dispose of as directed under heading 13.

Other information

Remove all sources of ignition - No smoking. Provide good ventilation. Keep unauthorized persons away from the spillage. Warning for slippery surface.



7. HANDLING AND STORAGE

Special properties and risks

The vapours are heavier than air and collect at floor level and low-lying areas. Flammable vapours that can combine with air to form an explosive mixture are produce at room temperature.

Advice for safe handling

Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary. Store away from direct sunlight, heat, fire and other sources of ignition. Take precautionary measures against static discharges. Use only electrical equipment with explosion protection. See the instructions on the label.

Storage instructions

Store in a dry, well-ventilated place away from heat, fire and direct sunlight. No smoking. Electrical installations and equipment must have explosion protection. Follow regulations for storage of flammable liquids. Keep cool and dry, away from food, drink and animal feeding stuffs. Unauthorised persons must not have access to the storage area. Keep in original packaging. Keep container tightly closed.



8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical name

Limit

Carbon black

3 mg/m 3

Ethylacetate

500 mg/m 3

Toluene

200 mg/m 3

Methyl ethyl ketone

150 mg/m 3

Solvent naphtha (petroleum), light

120 mg/m 3



Control procedures

Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. The use of a barrier cream is recommended.

Respiratory equipment

A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.

Eye protection

Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.

Protective gloves

Solvent-resistant gloves. Use a barrier cream on skin.

Skin and body protection

Solvent-resistant protective clothing.



9. PHYSICAL AND CHEMICAL PROPERTIES

Form/state

Liquid

Odour

Characteristic

Colour

Black

Solubility in water

Reacts with water

Flash point

-9 °C

Boiling point

77 °C

Explosion range

approx. 8.8-11.5 vol%

Vapour pressure

approx. 200 mbar at 20°C

Density

0.99 g/cm 3

Viscosity

< 16s/23°C/4 mm

Autoignition point

approx. 410°C

Vapour density (air=1)

approx. 2.5



10. STABILITY AND REACTIVITY

Stability

Can react with the moisture in the air. Keep away from moisture. Vapours can form explosive mixture with air.

Reacts with

Avoid contact with other chemical products. Avoid contact with strong acids, amines and oxidizing agents.

Hazardous decomposition products

In case or fire or intense heat, carbon dioxide, carbon monoxide, nitrous oxides and toxic fumes are produced. Risk of peroxide mixtures.



11. TOXICOLOGICAL INFORMATION

Inhalation

Irritating to the respiratory system. Inhalation may cause headaches, dizziness, drowsiness, muscular weakness, narcotic effects and, in exceptional cases, unconsciousness. Inhalation of high concentrations may damage the lever and kidneys and affect the central nervous system.

Skin

Prolonged or repeated skin contact defats the skin and may cause irritation and dermatitis. Substances in the product can be absorbed through the skin. Repeated exposure can cause sensitization and allergic reactions (eczema).

Eyes

Irritating to the eyes and may cause temporary damage.

Ingestion

If swallowed, may cause stinging in mouth and throat, nausea and stomach pains.

Sensitization

Sensitizing effects possible after inhalation or skin contact.



12. ECOLOGICAL INFORMATION

Mobility

Insoluble in water.

Ecotoxicity

Test data for primary component, methyl ethyl ketone:

Fish toxicity: Leuciscus idus LC50 4600 mg/l

Toxicity for daphnia: D.Magna EC50 7060 mg/l

Toxicity for bacteria: Pseudomonas putida EC0 1150 mg/l

Other information

Do not empty into water, drains or onto ground.



13. DISPOSAL CONSIDERATIONS

Disposal considerations

Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification. EWC-code 07 02 04, other organic solvents, washing liquids and mother liquors.



14. TRANSPORT INFORMATION

Road (ADR)

UN-no.: 1139

Hazardous goods

Marg no.

Class: 3, 5 (b)

Label

Hazard no.

Rail (RID)

UN-no.: 1139



Class: 3, 5 (b)

Label

Hazard no.

Sea (IMDG)

UN-no.: 1139

Hazardous goods

Class: 3.2

EmS: 3-05

Page

MFAG: 300

Label

Marine poll: No

Packaging group: II

Sub. Risk

IATA (air)

UN-no.: 1139

Hazardous goods

Class: 3

Sub. Risk

Label

Packaging group: II

Proper shipping name

Coating solution



15. REGULATORY INFORMATION

Labelling

Irritant, Highly flammable

Contains

Contains isocyanates. See information from manufacturer.

References

See provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics.



R-phrases

R11

Highly flammable.

R36

Irritating to eyes.

R66

Repeated exposure may cause skin dryness or cracking.

R67

Vapours may cause drowsiness and dizziness.

S-phases

S2

Keep out of the reach of children.

S16

Keep away from sources of ignition - No smoking.

S23

Do not breathe vapour/spray.

S37

Wear suitable gloves.

S46

If swallowed, seek medical advice immediately and show this container or label.

S51

Use only in well-ventilated areas.



16. OTHER INFORMATION

General information

This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.

Issued

2001-05-01




Material safety data sheet


1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product name

BETAWIPE VP04604

Manufacturer - supplier

SAAB-ANA Konsult AB

Box 1030

611 29 NYKÖPING

Tel: +46 (0) 155-24 94 82

Fax: +46 (0) 155-24 94 71

Tel (emergency): 112



2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient

CAS-no.

Content (%)

FM

FB

FH

R-phrases

3-mercaptopropyl-trimethoxysilane

4420-74-0

1-10

N



Xn

R21/22-51/53

3-(2-aminoethylamino)propyltrimethoxysilane

1760-24-3

1-10





Xi

R36/38-43

Isopropanol

67-63-0

80-100



F+

Xi

R11-36-67



Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment



3. HAZARDS IDENTIFICATION

Health hazards

Irritating to eyes, skin and respiratory system. May cause sensitisation and allergic reaction after skin contact. Breathing high concentrations may cause dizziness, headaches and nausea. Defats the skin and after prolonged or repeated contact cause the skin to dry and crack.

Fire hazards

Highly flammable.



4. FIRST AID MEASURES

Other information

Take off contaminated clothing immediately.

Inhalation

Move the casualty into fresh air. Seek medical advice immediately. Keep the casualty warm and allow to rest. Perform artificial respiration if the casualty stops breathing or breathes irregularly.

Skin

Wash skin immediately with soap and water. Seek medical advice if irritation persists.

Eyes

Flush eyes immediately with plenty of water for several minutes. Hold eyes wide open. Seek medical advice immediately.

Ingestion

Do not induce vomiting. Seek medical advice immediately.



5. FIRE-FIGHTING MEASURES

Suitable extinguishing media

Alcohol-resistant foam, carbon dioxide or water spray.

Unsuitable extinguishing media

Water jet.

Fire/explosions risks

Vapours can form an explosive mixture with air. In case of fire, flammable and irritating gases can form.

Special protective equipment for firefighters

Complete protective equipment including respiratory equipment.

Other information

Do not breathe fumes from the fire. Move containers in the vicinity of the fire immediately or cool with water.



6. SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions

Avoid contact with skin, eyes and clothes. Do not breathe vapours. Wear the prescribed protective equipment (see heading 8).

Environmental precautions

Keep the product away from drains, the ground and watercourses. Contact the appropriate authority immediately if the product enters drains, lakes or watercourses.

Methods for cleaning up

Soak up using non-flammable absorbent material such as sand, earth, kieselguhr or vermikulite. Dispose of as directed under heading 13.

Other information

Remove all sources of ignition - No smoking. Provide good ventilation. Keep unauthorized persons away from the spillage. Warning for slippery surface.



7. HANDLING AND STORAGE

Special properties and risks

The vapours are heavier than air and collect at floor level and low-lying areas. Flammable vapours that can combine with air to form an explosive mixture are produce at room temperature.

Advice for safe handling

Avoid contact with eyes, skin and clothing. Do not breathe vapours. Use only in well ventilated areas. Mechanical ventilation and spot extraction may be necessary. Store away from direct sunlight, heat, fire and other sources of ignition. Take precautionary measures against static discharges. Use only electrical equipment with explosion protection. See the instructions on the label.

Storage instructions

Store in a dry, well-ventilated place away from heat, fire and direct sunlight. No smoking. Electrical installations and equipment must have explosion protection. Follow regulations for storage of flammable liquids. Keep cool and dry, away from food, drink and animal feeding stuffs. Unauthorised persons must not have access to the storage area. Keep in original packaging. Keep container tightly closed.



8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Substance

Limit

Isopropanol

350 mg/m 3



Control procedures

Use only in well-ventilated areas. Spot extraction equipment or mechanical ventilation may be necessary. Do not smoke, eat or drink while working with the product. Good personal hygiene is essential. Wash hands before taking a break and on completion of the work. Take off contaminated clothing immediately. The use of a barrier cream is recommended.

Respiratory equipment

A full-face or half-face mask with filter for organic vapours must be used in case of high vapour concentrations or if ventilation is inadequate.

Eye protection

Close-fitting protective glasses with side shields must be used if there is a risk of direct contact or splashing.

Protective gloves

Solvent-resistant gloves. Use a barrier cream on skin.

Skin and body protection

Wear protective clothing if there is a risk of direct contact or splashes.



9. PHYSICAL AND CHEMICAL PROPERTIES

Form/state

Liquid

Odour

Alcohol

Colour

Colourless

Solubility in water

Miscible

Density

0.79 g/cm 3

Boiling point

82 °C

Flash point

13 °C

Explosion limits

2-12 vol. %

Vapour pressure

approx. 40 mbar at 20°C

Viscosity

approx. 50 s/23°C/2 mm

Autoignition point

approx. 425°C

Vapour density (air=1)

2.1



10. STABILITY AND REACTIVITY

Stability

Vapours can form explosive mixture with air.

Reacts with

Avoid contact with strong oxidizing agents.

Hazardous decomposition products

In case or fire or intense heat, carbon dioxide, carbon monoxide and toxic fumes are produced.



11. TOXICOLOGICAL INFORMATION

Inhalation

Irritating to the respiratory system. Inhalation may cause headaches, dizziness, drowsiness, muscular weakness, narcotic effects and, in exceptional cases, unconsciousness. Inhalation of high concentrations may damage the lever and kidneys and affect the central nervous system.

Skin

Prolonged or repeated skin contact defats the skin and may cause irritation and dermatitis. Repeated exposure can cause sensitization and allergic reactions (eczema).

Eyes

Irritating to the eyes and may cause temporary damage.

Ingestion

If swallowed, may cause stinging in mouth and throat, nausea and stomach pains as well as similar effect to inhalation.

Sensitization

Sensitizing effects possible after skin contact.



12. ECOLOGICAL INFORMATION

Degradability

The solvent, isopropanol, decomposes readily. The product also contains substances that do not readily decompose.

Bioaccumulation

The solvent, isopropanol, does not bioaccumulate. Data lacking for other components.

Ecotoxicity

Fish toxicity: LC50 > 100 mg/l (regarding isopropanol)

Other information

Do not empty into water, drains or onto ground.



13. DISPOSAL CONSIDERATIONS

Disposal considerations

Dispose of product waste as hazardous waste in accordance with regulations. Recommended method of destruction: incineration in facilities with flue-gas purification. EWC-code 07 01 04, other organic solvents, washing liquids and mother liquors. EWC-code 07 06 04, other organic solvents, washing liquids and mother liquors.



14. TRANSPORT INFORMATION

Road (ADR)

UN-no.: 1219

Hazardous goods

Marg no.

Class: 3, 3 (b)

Label

Hazard no.

Rail (RID)

UN-no.: 1219



Class: 3, 3 (b)

Label

Hazard no.

Sea (IMDG)

UN-no.: 1219

Hazardous goods

Class: 3.2

EmS: 3-06

Page

MFAG: 305

Label

Marine poll: No

Packaging group: II

Sub. Risk

IATA (air)

UN-no.: 1219

Hazardous goods

Class: 3

Sub. Risk

Label

Packaging group: II

Proper shipping name

Isopropanol mixture



15. REGULATORY INFORMATION

Labelling

Irritant, Highly flammable



R-phrases

R11

Highly flammable.

R36

Irritating to eyes.

R43

May cause sensitization by skin contact.

R67

Vapours may cause drowsiness and dizziness.

S-phases

S2

Keep out of the reach of children.

S7

Keep container tightly closed

S16

Keep away from sources of ignition - No smoking.

S26

In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

S36/37

Wear suitable protective clothing and gloves.

S46

If swallowed, seek medical advice immediately and show this container or label.



16. OTHER INFORMATION

General information

This material safety data sheet is only intended to provide guidance as to safe handling with regard to health, safety and the environment. The information contained in this material safety data sheet is not a specification of the product and must not be considered as a guarantee of any specific properties.

Issued

2001-05-07