30 04 736 Primer, etching

/ 9-3 (9400) / 2003 / 0. General / Chemicals / Technical data / 30 04 736 Primer, etching

Specifications

Standox 1K-Füllprimer. Acid-hardening. For normal and galvanized sheet metal. 1 litre can.

Saab application

Packaging

Transport

The product is classified as dangerous goods when transporting. Special regulations apply to packaging, marking and transport, therefore existing lead times cannot be guaranteed.

Directives

The product is flammable. May be hazardous if inhaled after frequent and repeated exposure. Dehydrates the skin. Avoid inhaling vapours/mist. Avoid skin contact. Make sure that ventilation is adequate.

Material safety data sheet

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Trade name	Standox 1K Primer Filler Beige
Range of application	Miscellaneous
Information provided by	DuPont Performance Coatings Scandinavia AB Tel: +46 (0) 31-57 68 00
Manufacturer - supplier	STANDOX GmbH Christbusch 45 D-42285 Wuppertal Tel: +49 202 2530-0 Tel. in case of emergency: +49 202 2530-6655

COMPOSITION/INFORMATION ON INGREDIENTS

Description	Mixture of synthetic binders.
Further information	R-phases in plain text can be found in section 16. To avoid misinterpretation when evaluating risks, do not add up the percentages.
Substances that make the product harmful	Se below.

Ingredient	CAS-no.	Content (%)	Hazard symbol	R-phrases
1-Propanol	000071-23-8	25.0-<50.0	Xi	41-67
Isobutyl alcohol	000078-83-1	15.0-<20.0	Xi	37/38-41-67
1-methoxi-2-propanol	000107-98-2	2.0-<3.0
Xylene, mixture	001330-20-7	1.0-<2.0	Xn	20/21-38

Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment

HAZARDS IDENTIFICATION

Adverse health effects	Irritant
Particular harmful effects for humans and the environment	Flammable. Irritating to skin. Risk of serious damage to eyes. Vapours may cause drowsiness and dizziness.

FIRST AID MEASURES

General advice	In case of symptoms or uncertainty, seek medical advice. If casualty is unconscious, do not administer medicine orally.
Inhalation	Give fresh air and rest. Keep warm. If breathing irregularly or not breathing give artificial respiration. If unconscious, place in recovery position and seek medical attention.
Skin	Remove contaminated clothing. Wash thoroughly with plenty of soap and water or other suitable detergent. Do not use solvents or thinners!
Eyes	Flush immediately with plenty of water for at least 15 minutes. Seek medical attention for a checkup.
Ingestion	Seek medical advice immediately. Drink plenty of water. Do not induce vomiting.

FIRE-FIGHTING MEASURES

Suitable extinguishing media	Foam (alcohol resistant), carbon dioxide, powder, water spray.
Extinguishing media that must not be used	Water jet.
Particular health hazards due to contact with the product, its products of combustion or gases that may form	Thick, black smoke forms in case of fire. Inhalation of harmful decomposition products may cause serious damage to health.
Special protective equipment for firefighters	Use self-contained respiratory equipment as appropriate.
Further information	Water may be used to cool unopened containers close to the fire.

SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions	Keep away from sources of ignition - No smoking. Do not breathe vapour. See section 7 and 8 for safety precautions.
Environmental precautions	Do not empty into drains. In case of contamination to watercourses and sewage networks, contact the appropriate authorities as specified by local regulations.
Methods for cleaning up	Absorb spillage with non-flammable absorbent material such as sand, earth, vermikulite or kieselguhr, and place in a suitable waste disposal container in accordance with local regulations. If possible, use a detergent for sanitation. Avoid solvents and thinners.

HANDLING AND STORAGE

Advice for safe handling	Avoid the formation of flammable or explosive solvent vapours. Do not exceed the admitted occupational exposure limits for the solvent components. The product must not be stored or used in the vicinity of naked flames, sparks or other sources of ignition. Take precautionary measures against static discharges when refilling and handling. Ground the container and piping. We recommend the use of antistatic clothing and shoes. Use only non-sparking tools. Avoid contact with eyes and skin. Do not breathe spray. When using do not eat, drink or smoke. See section 8 for personal protective equipment. Follow applicable safety regulations. If using a spray booth, all persons in the booth must use air-line breathing apparatus until the aerosol and solvent concentration is below the applicable limit.
Advice regarding protection against fire and explosion	The solvent vapours are heavier than air and spread at floor level. The vapours and air combine to form an explosive mixture.
Requirements of storage area and container	Keep well sealed in a cool, well-ventilated area. Keep away from sources of heat, sparks and naked flames. Reseal opened containers carefully and store upright to avoid leakage. Do not empty containers using compressed air.
Advice on storage with other materials	Keep away from strong acidic or alkali material and oxidizing agents.
Other advice on storage conditions	Must be stored in a container equivalent to the original container. Follow the directions on the label. Store at +5 to +30°C in a dry, well-ventilated area. Protect from heat and direct sunlight. Keep away from sources of ignition.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Technical measures	Use in a well ventilated area. In case of insufficient ventilation or the breaking of solvent exposure limits, wear suitable respiratory equipment. Exposure limits are available from the local authorities.
Control parameters	Se below.

Chemical identity	CAS-no.	Type	Limit	Unit
Isobutyl alcohol	000078-83-1	NGV	50	ml/m3
	"	NGV	150	mg/m3
	"	KGV	75	ml/m3
	"	KGV	250	mg/m3
1-methoxi-2-propanol	000107-98-2	NGV	50	ml/m3
	"	NGV	190	mg/m3
	"	KGV	75	ml/m3
	"	KGV	300	mg/m3
Xylene, mixture	001330-20-7	NGV	50	ml/m3
	"	NGV	200	mg/m3
	"	KGV	100	ml/m3
	"	KGV	450	mg/m3

Other information	The specified exposure limits are taken form limit lists current at the time of preparation of the material safety data sheet.
Respiratory equipment	If the solvent concentration in the premises exceeds the limit, use approved respiratory equipment.
Hand protection	Wear protective nitrile rubber gloves. In case of prolonged or repeated contact, use a barrier cream for solvents on exposed areas of skin. Follow the directions of the manufacturer.
Eye protection	Wear eye protection to protect from splashes into the eyes.
Skin and body protection	Wear antistatic clothing made of natural fibres (cotton, wool, etc.) or high-temperature-resistant synthetic fibres. Wash contaminated clothing prior to continued use.
Hygiene measures:	In case of contact with skin, wash thoroughly with soap and water.

PHYSICAL AND CHEMICAL PROPERTIES

Form/state	Liquid	Odour	Of solvent
Colour	Beige	Solubility in water	Insoluble
Density (at 20°C)	1.098 g/cm ³ (DIN 53217)	Flash point	24°C (DIN 53213)
Autoignition point	270°C (DIN 51794)	Lower explosion limits	1.90 vol. %
Upper explosion limits	9.83 vol. %	Vapour pressure (at 20°C)	8.60 hPa
Viscosity (at 23°C)	40-60 s (ISO 2431-1993 6 mm)	Solvent decomposition test	< 3% (ADR/RID/GGVS/GGVE)
Solvent content	approx. 58%

10.

STABILITY AND REACTIVITY

Unsuitable environments	Stable under recommended storage and handling conditions, see section 7. High temperatures may produce dangerous decomposition products such as carbon monoxide, carbon dioxide, fumes and nitrous oxides. Oxidizing agents, strong alkalis and strong acids may cause exothermic reactions.
Do not store with	Keep away from strong acidic and alkali substances and oxidizing agents, as these may cause an exothermic reaction.
Hazardous decomposition products:	High temperatures may produce dangerous decomposition products such as carbon monoxide, carbon dioxide, fumes and nitrous oxides

11.

TOXICOLOGICAL INFORMATION

Inhalation	Breathing solvent concentrations above the stated limits may cause damage to health such as irritated mucus membranes and respiratory system, and damage to the liver, kidneys and nervous system. Symptoms: headache, dizziness, drowsiness, muscular weakness and, in serious cases, unconsciousness.
Skin	Prolonged or repeated contact with the preparation may defat the skin and may cause non-allergic skin damage (contact dermatitis) and the absorption of solvent through the skin.
Eyes	Contact with the eyes may cause irritation and reversible damage to the eyes.
General	No toxicological information about the preparation is available. The harmfulness of the product is based on the individual constituents in accordance with recommended methods of evaluation from the authorities.

12.

ECOLOGICAL INFORMATION

General information

No data available for the product. Do not empty into drains. The product contains organically bound halogens, which can contribute to the AOX value.

13.

DISPOSAL CONSIDERATIONS

Recommendations	Do not empty into drains or watercourses.
Contaminated containers, recommendations	Empty containers should be left for scrapping or reconditioning. Containers that are not completely empty should be treated as environmentally hazardous waste and disposed of accordingly.
EWC code, description	080102: Waste paints and varnish free of halogenated solvents.

14.

TRANSPORT INFORMATION

Land (ADR/RID/ADR-S)	Class: Void Substance number: Void Goods description in container <= 450 l: Transport as per remark under E margin. 2301. Hazard symbol: Void
Sea (IMDG)	UN-no.: 1263 Class: 3.3 EmS-no.: 3-05 MFAG: 310 Marine pollutant: No Proper shipping name: PAINT
Air (ICAO/IATA)	UN-no.: 1263 Class: 3 Proper shipping name: PAINT

15.

REGULATORY INFORMATION

General information	In agreement with the regulations of the Swedish National Chemical Inspectorate and the Swedish National Inspectorate of Explosives and Flammables on the classification of harmful and flammable products, this product is labelled as follows:
Hazard symbol	Xi
Hazard indication	Irritant

R-phrases	Flammable. Irritating to skin. Risk of serious damage to eyes. Vapours may cause drowsiness and dizziness.
S-phases	Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Wear eye/face protection. If swallowed, seek medical advice immediately and show this container or label. Use in well-ventilated area. Do not swallow. Do not breathe vapour.
Special labelling for certain preparations	-
Other regulations, restrictions or prohibitions	-

16.

OTHER INFORMATION

R-phrases in plain text with number, section 2	R20/21	Harmful by inhalation and in contact with skin.
	R37/38	Irritating to respiratory system and skin.
	R38	Irritating to skin.
	R41	Risk of serious eye injuries
	R67	Vapours may cause drowsiness and dizziness.
General information	The information provided in this material safety data sheet is based on our best knowledge and meets the requirements of national guidelines and EU regulations. The current working conditions of the end user are outside our knowledge and control. The product must not be used for other purposes than those specified under heading 1, unless express, written permission is given. The user is duty bound to follow legislation and regulations. The information contained herewith describes safety requirements for the product. It does not guarantee any specific properties.
Information on the material safety data sheet	In agreement with the regulations of the Swedish National Chemical Inspectorate and the Swedish National Inspectorate of Explosives and Flammables on the classification of harmful and flammable chemical products.
Revised sections	15
Abbreviations	NA = Not applicable NE = Non-ignitable
Date	2002-08-06

30 04 736 Primer, etching

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