30 31 259 Alustick

/ 9-3 (9400) / 2003 / 0. General / Chemicals / Technical data / 30 31 259 Alustick

30 31 259 Alustick

Specifications

Alustick. 114 gramme tube.

Saab application

For repairing pores in, for example, the engine block.

Packaging

Transport

No restrictions apply when transporting this product.

Directives

The product is an irritant. Irritates eyes and skin. May cause allergic reaction in case of skin contact. Avoid skin and eye contact.

Material safety data sheet

IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE COMPANY/UNDERTAKING

Product name	ALU STICK
Product code	MM 704021
Description	Epoxy repair compound for aluminium and aluminium alloys. The product is in a convenient "stick" that contains both the base and hardener. Read the instructions before using the product!
Manufacturer - supplier	MEGA METAL (a division of AMATRON) Box 5318 102 47 STOCKHOLM Tel: +46 (0) 8-613 71 60 Fax: +46 (0) 8-20 48 40 Tel (emergency): 112

COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient	CAS-no.	Content (%)	Hazard symbol	R-phrases
Bisphenol-A-diglycidether (epoxy base)	25068-38-6	10-20	Xi	36/38, 43
2,4,6-Tri(dimethylaminomethyl) phenol (hardener)	90-72-2	1-5	Xi	22, 36/38
Aluminium	7429-90-5	5-10	F+, N	15, 17, 50, 53
Talc	14807-96-6	50-60

Key

FB/FH/FM = Hazard code for fire/health/environment

T+ = Very toxic

T = Toxic

C = Corrosive

Xn = Harmful

Xi = Irritant

V = Moderately harmful

IK = Not subject to labelling

E = Explosive

O = Oxidizing

F+ = Extremely flammable

F = Highly flammable

N = Dangerous for the environment

HAZARDS IDENTIFICATION

Adverse health effects	Irritating to eyes and skin. May cause sensitization by skin contact.
Adverse environmental effects	Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

FIRST AID MEASURES

General information	In general, if you are in any doubt or if the symptoms persist, seek medical advice. NEVER give an unconscious person anything to eat or drink.
Inhalation	Move to fresh air. If symptoms persist, seek medical advice.
Skin	Take off contaminated clothing and shoes. Wash the skin carefully for several minutes with soap and water. Never use an organic solvent.
Eyes	Remove any contact lenses and flush with plenty of soft, clean water for at least 10 minutes, keeping the eyelids wide apart. Seek medical advice as soon as possible.
Ingestion	If swallowed, rinse the mouth with water and drink large quantities of water or milk. Never induce vomiting. Seek medical advice.

FIRE-FIGHTING MEASURES

Suitable extinguishing media	Chemical powder, carbon dioxide, sand, foam or water spray.
Specific hazards	Fire produces toxic fumes. If the preparation is subjected to high temperatures, harmful products of decomposition can be released, such as carbon monoxide, carbon dioxide, vapours and nitrogen oxide.
Protective equipment	The people fighting the fire must be well equipped with self-contained breathing apparatus.

SPILLAGE/ACCIDENTAL RELEASE MEASURES

Personal precautions	Wear rubber gloves and protective goggles.
Environmental precautions	Spillage containing thermosetting plastic components must be dealt with and placed in a special waste container. The container must have a lid and be clearly and permanently marked with the text "Harmful waste".

HANDLING AND STORAGE

Advice for safe handling	Handle only in well-ventilated areas. As a fine powder suspended in the air, the substance can produce a dust explosion (AFS 1981:5).
Control procedures against fires	Keep the container tightly closed and keep away from sources of heat, sparks and open flames.
Recommended equipment and procedures	Observe the safety precautions specified on the label and standard work safety rules. Do not breathe vapours.
Storage	Keep container tightly closed in a dry, well-ventilated, frost-free place. Keep out of the reach of children.
Other information	The regulations regarding storage premises are applicable to workshops at which the product is handled. Epoxy product that polymerises on kneading. Read the instructions on the packaging before use. Follow the provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics, AFS 1996:4.

EXPOSURE CONTROLS/PERSONAL PROTECTION

Chemical identity	Limit	Type
Aluminium metal and oxide dust, total	5 mg/m ³	NGV
Aluminium metal and oxide dust, respiratable	2 mg/m ³	NGV
Talc dust, total	2 mg/m ³	NGV
Talc dust, respiratable	1 mg/m ³	NGV
Thermosetting plastic dust	3 mg/m ³	NGV

Technical measures	Ensure adequate ventilation, if possible through the use of extraction equipment at the workstations and a general air extractor.
Protective equipment (masks)	If ventilation is sufficient, protective masks are not necessary. If a protective mask is necessary, use a P2 particle filter.
Hand protection	In case of prolonged or repeated contact with the hands, wear suitable protective gloves. Use gloves made of butyl rubber, natural rubber, neoprene, polyethene or PVC.
Eye protection	Wear approved protective goggles if use makes contact with eyes likely. The form of the product (solid compound) means the likelihood of splashes into the eyes during normal use is low.

PHYSICAL AND CHEMICAL PROPERTIES

Form/state	Paste	Odour	Mild
Flash point	>200°C	Density	1, 015
Solubility in water	Immiscible

10.

STABILITY AND REACTIVITY

Conditions and material to avoid:	Avoid contact with oxidizing chemicals, strong acids and strong alkali.
Hazardous decomposition products	If the preparation is subjected to high temperatures, harmful products of decomposition can be released, such as carbon monoxide, carbon dioxide, vapours and nitrogen oxide.

11.

TOXICOLOGICAL INFORMATION

General information	Strongly sensitizing. May produce allergic contact eczema (up to mean molecular mass 908) on second exposure. May produce nettle rash.
LD50 acute for rat	>2000 mg/kg, equivalent to moderately harmful.
Eye (rabbit)	May irritate.
Skin (rabbit)	May irritate.
Skin (guinea pig)	May cause sensitization by skin contact.
Aluminium	Prolonged exposure to aluminium primarily damages the central nervous system. High exposure may cause alumiosis (A&H 1992:45, 1982:23, 1995:18). Aluminium is little absorbed by the body.
Bisphenol-A-diglycidether	is listed on the Swedish National Chemicals Inspectorate's observation list due suspicion of allergenic properties.
Talc dust	Can collect in the lungs after repeated exposure. Depleted lung function can result from occupational exposure to talc dust that is free of asbestos and silica. Asbestos and silica in talc dust can cause cancer (A&H 1992:2).

Toxicity on ingestion	LD50 Oral, rat
Bisphenol-A-diglycidether	914 mg/kg body weight
Tris-2,4,6-(dimethylaminomethyl) phenol	1200 mg/kg body weight

Toxicity on skin contact	LD50 Dermal, rabbit	LD50 Dermal, rat
Bisphenol-A-diglycidether	>25200 mg/kg body weight
Tris-2,4,6-(dimethylaminomethyl) phenol		1280 mg/kg body weight

12.

ECOLOGICAL INFORMATION

Ecotoxicity

Large quantities of uncured product must not come into contact with surface or ground water. In accordance with the new preparation directive, 1999/45/EU, the product is classed as dangerous for the environment (N), with R-phrases R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. No information for the product has been produced.

Aluminium and aluminium compounds

are considered to be the dominating reason for the death of fish in acid waters. The active aluminium compounds have shown to upset the fish's salt balance and cause suffocation since aluminium hydroxide precipitates on the gills reducing the uptake of oxygen into the blood. Aluminium is also associated with disrupting the breeding, above all eggshell thinning, of birds such as the flycatcher and other passerine that breed around lakes. Soluble aluminium compounds increase with reduced pH. Not readily degradable. The Nordic Council classes aluminium and aluminium compounds as follows: dangerous for the environment, very toxic for aquatic organisms and may cause long-term adverse effects in the aquatic environment.

Toxic substance	LC50 Fish 96h	LC50 Daphnia 48h	LC50 Algae 72h
Aluminium	2.6 mg/l water (species: brook trout)	1.4 mg/l water (species: Magna)	<0.2 mg/l water

Accumulative potential

BCF: 18

13.

DISPOSAL CONSIDERATIONS

Surplus	Spillage containing thermosetting plastic components must be dealt with and placed in a special waste container. The container must have a lid and be clearly and permanently marked with the text "Harmful waste". Dispose of waste in accordance with local regulations.
Contaminated packaging	Dispose of contaminated packaging in the same manner as the product. Cured material can be disposed of as construction waste.

14.

TRANSPORT INFORMATION

Transport the product in accordance with regulations: ADR for road transport, RID for rail transport, IMDG for marine transport and ICAO/IATA for air transport. The product does not require classification according to the above-mentioned regulations.

15.

REGULATORY INFORMATION

Classification	The preparation has been classified in accordance with the Council Directive <All preparations> 88/379/EEC with adjustments. The product consists of two components in the same packaging.
Labelling	Irritant.
Contains	Contains epoxy compounds. See information from manufacturer.

R-phrases	R36/38	Irritating to eyes and skin.
	R43	May cause sensitization by skin contact.
S-phases	S2	Keep out of the reach of children.
	S28	After contact with skin, wash immediately with plenty of soap and water.
	S37/39	Wear suitable gloves and eye/face protection
		For professional use only.
Special regulations.	Follow the provisions of the Swedish National Board of Occupational Safety and Health on thermosetting plastics, AFS 1996:4.

16.

OTHER INFORMATION

General information

Since the working conditions of the user are unknown to us, the information provided in this form is based on current knowledge and national and Council regulations. The product must not be used for purposes other than those specified under heading 1, unless written handling instructions are provided. The user is always responsible for taking all necessary safety precautions to fulfil the requirements of local legislation and regulations. The information provided in this form is a description of the safety measures required for our product and is not a guarantee of the properties of the product.

Issued

2001-03-28

30 31 259 Alustick

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